Semiconductor device and manufacturing method thereof

ABSTRACT

A method of manufacturing a semiconductor device includes forming a nanowire foundation layer on a semiconductor substrate. A first nanowire is formed on the nanowire foundation layer. A gate structure is formed over the nanowire foundation layer and wrapping the first nanowire. A second nanowire is formed on and in contact with the first nanowire in a bottom-up manner. A source/drain region is formed on the gate structure and wrapping the second nanowire.

PRIORITY CLAIM AND CROSS-REFERENCE

This application claims priority to U.S. Provisional Application Ser. No. 62/593,096, filed Nov. 30, 2017, which is herein incorporated by reference.

BACKGROUND

As the semiconductor industry has progressed into nanometer technology process nodes in pursuit of higher device density, higher performance, lower power consumption and lower costs, challenges from both fabrication and design issues have resulted in the development of three-dimensional designs, such as a fin field effect transistor (finFET). In a finFET device, it is possible to utilize additional sidewalls and to suppress a short channel effect.

Another candidate is a vertical field effect transistor (VFET) device. While a finFET device has a channel extending in a horizontal direction as a fin, in a VFET, a channel extends in a vertical direction (normal direction to a substrate surface). When a VFET is a gate all around (GAA) device, all of the channel layer (surfaces of the channel layer) can be subject to gate control. A GAA device, such as a GAA MOSFET (or MISFET) device, includes a very narrow cylindrical channel body. In particular, a vertical type GAA device (VGAA) having a channel extending in a vertical direction is a promising device for a candidate for low power SRAM applications.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIG. 1 is a flow chart illustrating a method of fabricating a semiconductor device in accordance with some embodiments of the instant disclosure;

FIGS. 2A through 30B are perspective views and top views respectively of a portion of a semiconductor device at various stages in a vertical nanowire gate-all-around fabrication process in accordance with some embodiments of the instant disclosure;

FIG. 31 is a perspective view of a portion of a vertical nanowire gate-all-around semiconductor device in accordance with some embodiments of the instant disclosure; and

FIG. 32 is a schematic cross-sectional diagram illustrating a stacked VGAA SRAM on a CMOS in accordance with some embodiments of the instant disclosure.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.

The gate all around (GAA) transistor structures may be patterned by any suitable method. For example, the structures may be patterned using one or more photolithography processes, including double-patterning or multi-patterning processes. Generally, double-patterning or multi-patterning processes combine photolithography and self-aligned processes, allowing patterns to be created that have, for example, pitches smaller than what is otherwise obtainable using a single, direct photolithography process. For example, in one embodiment, a sacrificial layer is formed over a substrate and patterned using a photolithography process. Spacers are formed alongside the patterned sacrificial layer using a self-aligned process. The sacrificial layer is then removed, and the remaining spacers may then be used to pattern the GAA structure.

Referring to FIG. 1, a flow chart of a method 10 of fabricating a semiconductor device in accordance with some embodiments of the instant disclosure. The method 10 begins with operation 110 in which a first type nanowire foundation layer and a second type nanowire foundation layer are formed on a semiconductor substrate. The method 10 continues with operation 120 in which first nanowires and second nanowires are respectively formed on the first type nanowire foundation layer and the second type nanowire foundation layer. Subsequently, operation 130 is performed that forming a gate structure over the first and second nanowire foundation layers and wrapping the first and second nanowires. The method 10 continues with operation 140 in which third and fourth nanowires are respectively grown on and in contact with the first and second nanowire in a bottom-up manner. The method 10 continues with operation 150 in which source/drain regions are formed on the gate structure and wrapping the third and fourth nanowires. The method 10 continues with operation 160 in which fifth and sixth nanowires are respectively grown on and in contact with the third and fourth nanowires in a bottom-up manner. The method 10 continues with operation 170 in which a word line is formed to wrap the fifth nanowires. The method 10 continues with operation 180 in which seventh nanowires are formed on and in contact with the fifth nanowires. The method 10 continues with operation 190 in which bit line is formed to wrap the seventh nanowires. The discussion that follows illustrates embodiments of semiconductor devices that can be fabricated according to the method 10 of FIG. 1. While method 10 is illustrated and described below as a series of acts or events, it will be appreciated that the illustrated ordering of such acts or events are not to be interpreted in a limiting sense. For example, some acts may occur in different orders and/or concurrently with other acts or events apart from those illustrated and/or described herein. In addition, not all illustrated acts may be required to implement one or more aspects or embodiments of the description herein. Further, one or more of the acts depicted herein may be carried out in one or more separate acts and/or phases.

GAA field-effect transistors (FETs) show advantages in scaling down the ever more complex semiconductor device. Unlike conventional approach of gate pitch reduction or metal track pitch scaling, VGAA FET does not compromise device performance and even allows denser packaging potential. A two-tier vertical integration in a static random access memory (SRAM) device means the SRAM ports on the top layer and positive supply voltage Vdd and ground (negative) supply voltage Vss are at the bottom, such that lateral expanding is minimized. In some embodiments, the SRAM area scaling down can be smaller than about 0.005 μm².

FIGS. 2A through 29B are perspective views and top views respectively of a semiconductor device at various stages in a vertical nanowire GAA fabrication process in accordance with some embodiments of the instant disclosure. Reference is made to FIGS. 2A and 2B and operation 110 in FIG. 1. A fin structure is provided, and the fin structure includes a plurality of fins 24 a and 24 b on a semiconductor substrate 20. In some embodiments, the semiconductor substrate 20 may include silicon (Si). Alternatively, the semiconductor substrate 20 may include germanium (Ge), silicon germanium, gallium arsenide (GaAs) or other appropriate semiconductor materials. Also alternatively, the semiconductor substrate 20 may include an epitaxial layer. For example, the semiconductor substrate 20 may have an epitaxial layer overlying a bulk semiconductor. Further, the semiconductor substrate 20 may be strained for performance enhancement. For example, the epitaxial layer may include a semiconductor material different from those of the bulk semiconductor such as a layer of silicon germanium overlying a bulk silicon or a layer of silicon overlying a bulk silicon germanium formed by a process including selective epitaxial growth (SEG). Furthermore, the semiconductor substrate 20 may include a semiconductor-on-insulator (SOI) structure such as a buried dielectric layer. Also alternatively, the semiconductor substrate 20 may include a buried dielectric layer such as a buried oxide (BOX) layer, such as that formed by a method referred to as separation by implantation of oxygen (SIMOX) technology, wafer bonding, SEG, or other appropriate method. In various embodiments may include any of a variety of substrate structures and material. Isolation regions 22 are formed on the semiconductor substrate 20 and are used to define the active regions of the semiconductor device. In some embodiments, the isolation regions 22 may be shallow trench isolation structures. In some embodiments, the top surfaces of the fins 24 a and 24 b are flat while the top surfaces of the isolation regions 22 are convex.

Reference is made to FIGS. 3A and 3B. A planarization process is performed to the fin structure, followed by the fin recession. The planarization process may be for example a chemical mechanical polishing (CMP) process to bring the top surface of the fins 24 a and 24 b and the isolation regions 22 substantially planar. After planarization, the fin 24 a is recessed. The fin recession process in this stage involves a number of the fins 24 a and 24 b but not all. For example, as shown in FIGS. 3A and 3B, the fin 24 a is recessed, while the fin 24 b remain un-recessed at this stage. A photolithography process may be used to cover up and protect the fin 24 b when the fin recession to the fin 24 a is performed. The fin recession to the fin 24 a results information of a shallow recession between the isolation regions 22 and on top of the fin 24 a such that the top surface of the fin 24 a is lower than the isolation regions 22 and the fin 24 b.

After the fin recession, a first type nanowire foundation layer 242 fills in the shallow recession over the fin 24 a. In some embodiments, the first type nanowire foundation layer 242 may be deposited by epitaxially growing an n-doped channel material or a p-doped channel material depending on the semiconductor device structure. For example, the first type nanowire foundation layer 242 may include an n-doped InAs channel material for an N-type channel. After the first type nanowire foundation layer 242 is formed, the top surface of the first type nanowire foundation layer 242 and the fin 24 b are substantially coplanar.

Reference is made to FIGS. 4A and 4B. Similarly, the fin 24 b is then recessed to form a shallow recession between the isolation regions 22 and the fin 24 b. A photolithography process may be used to cover up and protect the first type nanowire foundation layer 242 when the fin recession to the fin 24 b is performed. After the fin recession, a second type nanowire foundation layer 244 fills in the shallow recession over the fin 24 b. In some embodiments, the second type nanowire foundation layer 244 may be deposited by epitaxially growing an n-doped channel material or a p-doped channel material depending on the MOS device structure. For example, the second type nanowire foundation layer 244 may include a p-doped Ge channel material for a P-type channel. After the second type nanowire foundation layer 244 is formed, the top surfaces of the first type nanowire foundation layer 242, the second type nanowire foundation layer 244, and the isolation regions 22 are substantially coplanar.

Reference is made to FIGS. 5A and 5B. A nanowire template 26 is formed on the structure of FIGS. 4A and 4B. For example, a template layer is formed and then patterned to form the nanowire template 26. Examples of the nanowire template 26 materials may be dielectric and may include, but not limited, silicon oxide, silicon nitride, silicon oxynitride, or combination thereof. The nanowire template 26 is formed with a pattern that exposes a portion of the underlying first type nanowire foundation layer 242 and the second type nanowire foundation layer 244. In some embodiments, as shown in FIG. 5B, the nanowire template 26 is formed with through holes 26 a and 26 b. The through holes 26 a are aligned over the first type nanowire foundation layer 242, and the through holes 26 b are aligned over the second type nanowire foundation layer 244. That is, the through holes 26 a expose the first type nanowire foundation layer 242, and the through holes 26 b expose the second type nanowire foundation layer 244. The pattern of the nanowire template 26 is later used for nanowire formation (see FIGS. 6A and 6B). The pattern of the nanowire template 26 may adapt to different designs as long as the underlying first type nanowire foundation layer 242 and second type nanowire foundation layer 244 are exposed through the pattern such that the growth of vertical nanowires initiates from the first type nanowire foundation layer 242 and the second type nanowire foundation layer 244.

Reference is made to FIGS. 6A and 6B and operation 120 in FIG. 1. First nanowires 28 a and second nanowires 28 b are grown on the semiconductor substrate 20 in a bottom-up manner. In some embodiments, the first and second nanowires 28 a and 28 b are grown with a precursor containing trimethylindium (TMIn) in atomic fraction of 2.5×10⁻⁶ and tributylarsene (TBA) and/or arsene (As₃H) in atomic fraction of 2.5×10⁻⁴ under 545° C. The ratio between group V-III material in the precursor satisfies III/V is in a range from about 2 to about 15 and may be equal to 100. This ratio of group V-III material in the precursor is the same reaction condition used in the formation of silicon (111). The first and second nanowires 28 a and 28 b protrude out of the through holes 26 a and 26 b of the nanowire template 26, extending substantially perpendicularly to the nanowire template 26. A photolithography process may be used in the nanowire formation process. When the first nanowires 28 a are formed, a mask layer (not shown) covers up the through holes 26 b (before the formation of the second nanowires 28 b) or the second nanowires 28 b (after the formation of the second nanowires 28 b). When the second nanowires 28 b are formed, a mask layer (not shown) covers up the through holes 26 a (before the formation of the first nanowires 28 a) or the first nanowires 28 a (after the formation of the first nanowires 28 a). In this way, the first nanowires 28 a adopt the characteristics of the first type nanowire foundation layer 242, and the second nanowires 28 b adopt the second type nanowire foundation layer 44. The first and second nanowires 28 a and 28 b resemble pillars standing upwardly from the nanowire template 26. This process allows different types of nanowires to be formed on the same surface and be arranged in a compact space. The number and density of the nanowires are determined by the pattern of the nanowire template 26. As shown in FIGS. 6A and 6B, a total of four cylindrical nanowires is formed. The number of the nanowires may be more than four, for example, three in a row, and the instant disclosure is not limited thereto. In some embodiments, the first nanowires 28 a may be made of InAs, and the second nanowires 28 b may be made of Ge.

Reference is made to FIGS. 7A and 7B and operation 130 in FIG. 1. A gate dielectric layer 30 is formed on the structure of FIGS. 6A and 6B. The gate dielectric layer 30 is blanket deposited and conforms to the first and second nanowires 28 a and 28 b and the nanowire template 26. The contour of the first and second nanowires 28 a and 28 b is visible as individual pillar on the semiconductor substrate 20 after the deposition of the gate dielectric layer 30. In some embodiments, the gate dielectric layer 30 includes a passivation layer and a high-k dielectric layer over the passivation layer.

Reference is made to FIGS. 8A and 8B. A metal gate layer 32 is deposited on the gate dielectric layer 30. The metal gate layer 32 is blanket deposited on the semiconductor substrate 20 and conformal to the first and second nanowires 28 a and 28 b and on the surface of the nanowire template 26. In some embodiments, the metal gate layer 32 is deposited by for example atomic layer deposition (ALD). As shown in FIG. 8B, the semiconductor substrate 20 is covered up by the metal gate layer 32, and the underlying materials are covered. The metal gate layer 32 includes any metal material suitable for forming a metal gate or portion thereof, including work function layers, liner layers, interface layers, seed layers, adhesion layers, barrier layers or the like.

Reference is made to FIGS. 9A and 9B. A removal process (such as etching) is performed to remove portions of the metal gate layer 32 and the gate dielectric layer 30. A directional etching process, for example, dry etch is performed. The directional etching removes the material being etched at different rates in different directions. That is, directional etching does not horizontally as well as vertically into the material, but rather etches in substantially a single direction. The etching process leaves the surface of the nanowire template 26 substantially clear of the metal gate layer 32 and the gate dielectric layer 30, and one terminal of the first and second nanowires 28 a and 28 b is exposed. As shown in FIG. 9B, the nanowire template 26 can be seen from the top view, and the first and second nanowires 28 a and 28 b are wrapped by the gate dielectric layer 30 and the metal gate layer 32. The middle portion of the first and second nanowires 28 a and 28 b are wrapped by the gate dielectric layer 30 and the metal gate layer 32. The bottom portion of the first and second nanowires 28 a and 28 b, which is closer to the nanowire template 26, is wrapped by the gate dielectric layer 30 but not the metal gate layer 32, such that a ring of the gate dielectric layer 30 appears between the metal gate layer 32 and the nanowire template 26 to isolate the metal gate layer 32 and the nanowire template 26. The top portion of the first and second nanowires 28 a and 28 b, which is opposite to the nanowire template 26, is exposed after the etching process as shown in FIG. 9A. The top portion of the first and second nanowires 28 a and 28 b is free of the gate dielectric layer 30 and the metal gate layer 32. Unlike the bottom portion, the gate dielectric layer 30 and the metal gate layer 32 terminate at the same position on the wall of the first and second nanowires 28 a and 28 b. Before the etching process, the first and second nanowires 28 a and 28 b are linked by the gate dielectric layer 30 and the metal gate layer 32. After the etching process, the first and second nanowires 28 a and 28 b are independent from each other without the connection made by the metal gate layer 32. Each of the first and second nanowires 28 a and 28 b is encircled by an inner ring of gate dielectric layer 30 and an outer ring of the metal gate layer 32.

Reference is made to FIGS. 10A and 10B. A filling metal 34 is deposited. The filling metal 34 is deposited on the semiconductor substrate 20 to cover up the entire first and second nanowires 28 a and 28 b. The thickness of the filling metal 34 is at least the same as the height of the first and second nanowires 28 a and 28 b. After the filling metal 34 deposition, a planarization process is performed. The planarization process may be chemical mechanical polishing (CMP). This planarization process cuts short the height of the first and second nanowires 28 a and 28 b (i.e., the removal of the top portion) and continues to a level in which the gate dielectric layer 30 and the metal gate layer 32 come into view again as shown in FIG. 10B.

Reference is made to FIGS. 11A and 11B. A selective recession process is performed. In order to reveal the first and second nanowires 28 a and 28 b, the surrounding materials are recessed. The surrounding materials include the outermost filling metal 34, the metal gate layer 32 and the gate dielectric layer 30. The recessing process may be achieved by selective etching, such that the first and second nanowires 28 a and 28 b are retained and protrude upwardly from the surface level after the recessing.

Reference is made to FIGS. 12A and 12B. A spacer 36 is formed on the structure of FIGS. 11A and 11B. Examples of spacer material include dielectric materials including, but not limited to, Si₃N₄ and SiO₂. The spacer 36 is conformingly formed on the semiconductor substrate 20. The top surface of the filling metal 34 and the protruding first and second nanowires 28 a and 28 b are underlying the spacer 36. The protruding first and second nanowires 28 a and 28 b result in the bumps in the spacer 36 contour as shown in FIG. 12A.

Reference is made to FIGS. 13A and 13B. The gate materials are patterned. A photolithography and patterning process is performed to form the gate structure 40 as shown in FIG. 13A. The photolithography and patterning process results in the exposure of the isolation regions 22, the first type nanowire foundation layer 242, the second type nanowire foundation layer 244, the gate dielectric layer 30, the metal gate layer 32, and the filling metal 34. In some embodiments, the gate patterning process also lead to portions of the metal gate layer 32 exposure from behind the filling metal 34. In some embodiments, the metal gate layer 32 may not be exposed after gate patterning. As shown in FIG. 13B, the gate structure 40 stands in the central region, and the first nanowires 28 a are disconnected through the filling metal 34 and the spacer 36. One of the first nanowires 28 a remains connected with one of the second nanowire 28 b, which stands in proximity to the first nanowires 28 a, through the filling metal 34 and the spacer 36. Likewise, the other pair of first nanowire 28 a and second nanowire 28 b makes the same connection but in mirror image.

In terms of SRAM arrangement, the gate structure 40 contains two cross couple inverters, including two pull-up gates and two pull-down gates. Each of the inverters resembles a shape of L. One leg of the L crosses between the first nanowire 28 a and the second nanowire 28 b, substantially perpendicular to the underlying first and second type nanowire foundation layer 242 and 244. The other leg of the L extends in parallel to the lengthwise direction of the first and second type nanowire foundation layer 242 and 244. The two cross couple inverters together form a square-like enclosure but leave gaps in between. The gaps between the cross couple inverters reveal the first and second type nanowire foundation layers 242 and 244 respectively as shown in FIG. 13B.

Reference is made to FIGS. 14A and 14B. An interlayer dielectric layer 38 is deposited on the semiconductor substrate 20. For the sake of clarity, the interlayer dielectric layer 38 is depicted in dotted line and seen through to show the gate structure 40 there within. After the deposition of the interlayer dielectric layer 38, a planarization process, for example, CMP is performed. The bumps of the spacer 36 are flattened in the planarization process, and the underlying first and second nanowires 28 a and 28 b are exposed as shown in FIG. 14B.

Reference is made to FIGS. 15A and 15B. Contact holes 43 are formed on the gate structure 40. A photolithography and patterning process is performed to form the contact holes 43 so as to expose portions of the filling metal 34 that underlies the spacer 36. Each one of the cross couple inverters has at least one contact hole 43, and the contact hole 43 is positioned between the two first nanowires 28 a and between the two second nanowires 28 b as shown in FIG. 15B. In some other embodiments, however, the position of the contact holes 43 are not respectively between the two first nanowires 28 a and the two second nanowires 28 b. Embodiments fall within the present disclosure if the contact holes 43 respectively expose portions of the filling metal 34.

Reference is made to FIGS. 16A and 16B. A contact metal fills in the contact holes 43 to form the gate vias 44. The gate vias 44 allows electrical connection between an upper level and the gate structure 40.

Reference is made to FIGS. 17A and 17B and operation 140 in FIG. 1. Third and fourth nanowires 48 a and 48 b are formed in a bottom-up manner. The spacer 36 is used as a template similar to the nanowire template 26 (see FIGS. 5A and 5B). The spacer 36 reproduces the pattern of the nanowire template 26, in which the first nanowires 28 a is now acting as the first type nanowire foundation layer 242 and the second nanowires 28 b is now acting as the second type nanowire foundation layer 244. The third and fourth nanowires 48 a and 48 b are respectively grown according to the pattern of the first and second nanowires 28 a and 28 b underlying the spacer 36. The third and fourth nanowires 48 a and 48 b may be seen as an extension of the first and second nanowires 28 a and 28 b. A photolithography process may be used for separately growing the third and fourth nanowires 48 a and 48 b depending on the types of nanowires. The third and fourth nanowires 48 a and 48 b are formed into the source/drain nanowires. In some embodiments, the third nanowires 48 a may be made of InAs, and the fourth nanowires 48 b may be made of Ge.

Reference is made to FIGS. 18A and 18B and operation 150 in FIG. 1. A contact metal layer 52 is deposited on the third and fourth nanowires 48 a and 48 b, such that the gate vias 44 of FIGS. 17A and 17B are in contact with the contact metal layer 52. Unlike the gate structure 40, the third and fourth nanowires 48 a and 48 b are directly wrapped by the contact metal layer 52 without the gate dielectric layer. The contact metal layer 52 conforms to the shape of the third and fourth nanowires 48 a and 48 b as four pillars standing on the spacer 36.

Reference is made to FIGS. 19A and 19B. A filling metal 54 is deposited. The filling metal 54 is blanket deposited on the structure of FIGS. 18A and 18B. A planarization process is then performed to expose both the third and fourth nanowires 48 a and 48 b and the contact metal layer 52 as shown in FIG. 19B.

Reference is made to FIGS. 20A and 20B. A selective recession process is performed. In order to reveal third and fourth nanowires 48 a and 48 b, the surrounding materials are recessed. The surrounding materials include the outermost filling metal 54 and the contact metal layer 52. The recessing process may be achieved by selective etching, such that the third and fourth nanowires 48 a and 48 b are retained and protrude upwardly from the surface level after the recessing.

Reference is made to FIGS. 21A and 21B. A spacer 56 is formed on the third and fourth nanowires 48 a and 48 b and the filling metal 54. Examples of spacer material include dielectric material including but not limited to Si₃N₄ and SiO₂. The spacer 56 conforms to the protruding third and fourth nanowires 48 a and 48 b, resulting in bumps in the spacer 56 contour as shown in FIG. 21A.

Reference is made to FIGS. 22A and 22B. The source/drain materials are patterned. A photolithography and patterning process is performed to form the source/drain region 60 as shown in FIG. 22A. The photolithography and patterning process results in the exposure of the interlayer dielectric layer 38, the contact metal layer 52, and the filling metal 54. In some embodiments, the contact metal layer 52 may not be exposed after source/drain patterning. As shown in FIG. 22B, the source/drain region 60 stands in the central region and overlaps the gate structure 40. The source/drain region 60 has similar configuration as the gate structure 40, but the orientation is different. The source/drain region 60 is the mirror image of the spacer 36 of the gate structure 40. Gaps are formed between the two segments of the source/drain region 60, and the gaps reveal the underlying spacer 36 as shown in FIG. 22B. The source/drain region 60 is electrically connected to the third nanowires 48 a and the fourth nanowires 48 b.

Reference is made to FIGS. 23A and 23B. An interlayer dielectric layer 58 is deposited on the source/drain region 60. For the sake of clarity, the interlayer dielectric layer 58 is depicted in dotted line and seen through to show the source/drain region 60 therewithin. After the deposition of the interlayer dielectric layer 58, a planarization process, for example, CMP is performed. The bumps of the spacer 56 are flattened in the planarization process, and the underlying third and fourth nanowires 48 a and 48 b are exposed as shown in FIG. 23B.

Reference is made to FIGS. 24A and 24B and operation 160 in FIG. 1. Fifth and sixth nanowires 68 a and 68 b are formed in a bottom-up manner. The spacer 56 is used as a template similar to the nanowire template 26 (see FIGS. 5A and 5B). The spacer 56 reproduces the pattern of the nanowire template 26, in which the third and fourth nanowires 48 a and 48 b are now acting as the first type nanowire foundation layer 242 and second type nanowire foundation layer 244 respectively. The fifth and sixth nanowires 68 a and 68 b are grown according to the pattern of the first nanowire 28 a (third nanowire 48 a) and second nanowires 28 b (fourth nanowire 48 b). The first type nanowire foundation layer 242 and second type nanowire foundation layer 244 are directly used to grow the first nanowires 28 a and second nanowires 28 b. The first and second nanowires 28 a and 28 b are then used to grow the third and fourth nanowires 48 a and 48 b respectively. Subsequently, the third and fourth nanowires 48 a and 48 b are used to grow the fifth and sixth nanowires 68 a and 68 b. The pattern of the first type nanowire foundation layer 242 and second type nanowire foundation layer 244 is carried over through the first, second, third and fourth nanowires 28 a, 28 b, 48 a, and 48 b to the fifth and sixth nanowires 68 a and 68 b. The fifth and sixth nanowires 68 a and 68 b may be seen as an extension of the first and second nanowires 28 a and 28 b. A photolithography process may be used for separately growing the fifth and sixth nanowires 68 a and 68 b. In some embodiments, the fifth nanowires 68 a may be made of InAs, and the sixth nanowires 68 b may be made of Ge.

Reference is made to FIGS. 25A and 25B and operation 170 in FIG. 1. A gate dielectric layer 70, a metal gate layer 72 and a filling metal 74 are formed on the spacer 56. The gate dielectric layer 70 and metal gate layer 72 conform to the fifth and sixth nanowires 68 a and 68 b. The fifth and sixth nanowires 68 a and 68 b undergo similar process as described in FIGS. 9A, 9B, 10A and 10B. A ring of the gate dielectric layer 70 is left between the metal gate layer 72 and the spacer 56. The filling metal 74 is deposited on the spacer 56 and the interlayer dielectric layer 58 to cover up the entire fifth and sixth nanowires 68 a and 68 b. After the filling metal 34 deposition, a planarization process is performed. This planarization process cuts short the height of the fifth and sixth nanowires 68 a and 68 b (i.e., the removal of the top portion thereof) and continues to a level in which the gate dielectric layer 70 and the metal gate layer 72 come into view again as shown in FIG. 25B.

Reference is made to FIGS. 26A and 26B. A spacer 76 is formed on the filling metal 74. A selective recession process is performed before the deposition of the spacer 76. In order to reveal one terminal of the fifth and sixth nanowires 68 a and 68 b, the surrounding materials are recessed. The surrounding materials include the outermost filling metal 74, metal gate layer 72 and gate dielectric layer 70. After the recessing process the fifth and sixth nanowires 68 a and 68 b are retained and protrude upwardly from the surface level of the filling metal 74.

Reference is still made to FIGS. 26A and 26B. The spacer 36 is then conformingly deposited on the filling metal 74. The top surface of the filling metal 74 and the protruding fifth and sixth nanowires 68 a and 68 b are underlying the spacer 76. A photolithography and patterning process is performed to form the word line 80. The word line patterning process results in the removal of filling metal 74, the metal gate layer 72 and the gate dielectric layer 70 from the sixth nanowires 68 b. The sixth nanowires 68 b are exposed on the spacer 56. The fifth nanowires 68 a are wrapped up by the gate dielectric layer 70, the metal gate layer 72, and the filling metal 74, and the top portion of the fifth nanowire 68 a, which is free of the gate dielectric layer 70, the metal gate layer 72 and the filling metal 74, are surrounded by the spacer 76, in which the bumps are formed. A selective etching may be used to achieve the pattern as shown in FIGS. 26A and 26B. The word line 80 extends along a direction that is similar to the first type nanowire foundation layer 242 and overhangs the gate structure 40 and source/drain region 60 with a lengthy, narrow strip configuration.

Reference is made to FIGS. 27A and 27B. The sixth nanowires 68 b are removed. In some embodiments, a photoresist layer (not shown) is used to cover up the word line 80, and an etching is performed to remove the standing alone sixth nanowires 68 b from the spacer 56 atop. The removal of the sixth nanowires 68 b results in the exposure of the underlying fourth nanowires 48 b of the source/drain region 60. In some other embodiments, the sixth nanowire removal operation can be omitted if the sixth nanowires 68 b are not grown in the operation of FIG. 24A.

Reference is made to FIGS. 28A and 28B. An interlayer dielectric layer 78 is deposited on the existing interlayer dielectric layer 58. For the sake of clarity, the interlayer dielectric layer 78 is depicted in dotted line and seen through to show the word line 80 therewithin. After the deposition of the interlayer dielectric layer 78 a planarization process is performed. The bumps of the spacer 76 are flattened in the planarization process, and the underlying fifth nanowires 68 a are exposed as shown in FIGS. 28A and 28B.

Reference is made to FIGS. 29A and 29B and operation 180 in FIG. 1. The spacer 76 and fifth nanowires 68 a are used as the nanowire template for the bottom-up growth of the seventh nanowires 88 a. The sixth nanowires 68 b are removed, and the fourth nanowires 48 b are buried under the interlayer dielectric layer 78 such that only the first type nanowire is reproduced in this stage. In some embodiments, the seventh nanowires 88 a may be made of InAs.

Reference is made to FIGS. 30A and 30B and operation 190 in FIG. 1A. Bit line 100 is formed on the word line 80 and wrapping the seventh nanowires 88 a. The formation of the bit line 100 follows similar process as the formation of the word line 80. The difference between the bit line 100 and the word line 80 arises from the absence of the gate dielectric layer and the orientation, configuration of the filling metal 94 and the spacer 96. As such, the bit line 100 is electrically connected to the seventh nanowires 88 a. After a photolithography and patterning process to form the bit line 100, the metal layer 92 that surrounds the seventh nanowires 88 a is exposed, and the bit line 100 includes two independent strips, each strip having one of the seventh nanowires 88 a. The seventh nanowires 88 a are not connected through the filling metal 94 and the spacer 96. The bitline 100 is substantially perpendicular to the word line 80 and overhanging the word line 80. Subsequently, an interlayer dielectric layer 98 is deposited. A planarization process is then performed to remove the top portions of the interlayer dielectric layer 98 and the spacer 96 until the seventh nanowires 88 a are exposed as shown in FIG. 30B. The spacer 96 and the exposed seventh nanowires 88 a can be used as a nanowire template for the growth of another nanowire formed thereon. The semiconductor device includes the cross couple inverters (the first and second type nanowire foundation layers 242 and 244, the gate structure 40 and the source/drain region 60) at the lower level and the pass gate transistors (the source/drain region 60, the word line 80, and the bit line 100) at the upper level overlying the cross couple inverters as an SRAM cell.

Reference is made to FIG. 31. FIG. 31 is a simplified view of FIG. 23A including the gate structure 40 and source/drain region 60 of the cross couple inverters. The nanowire template 26 and the spacers 36 and 56 of FIG. 23A are omitted in the diagram. The first and second type nanowire foundation layer 242 and 244 and the isolation regions 22 are labelled in FIG. 31. The pull-down transistors are designated as PD1 and PD2, the pull-up transistors are designated as PU1 and PU2, and gate, source/drain regions are designated as G, S, D respectively.

Reference is made to FIGS. 30A and 31. The semiconductor device realizes the vertical gate all around configuration for 6T SRAM architecture. Specifically, the semiconductor device includes 6 transistors PD1, PD2, PU1, PU2, PG1, and PG2. The transistors PD1, PD2, PG1, and PG2 are N-type transistors, and the transistors PU1 and PU2 are P-type transistors. The pull-down transistor PD1 includes a gate and source/drain regions. The first type nanowire foundation layer 242 serves as a source/drain region of the transistor PD1, one of the source/drain regions 60 serves as another source/drain region of the transistor PD1, and one of the gate structure 40 serves as the gate of the transistor PD1. The pull-up transistor PU1 includes a gate and source/drain regions. The second type nanowire foundation layer 244 serves as a source/drain region of the transistor PU1, one of the source/drain regions 60 serves as another source/drain region of the transistor PU1, and one of the gate structure 40 serves as the gate of the transistor PU1. The transistors PD1 and PU1 share the same gate structure 40 and the same source/drain region 60, and form an inverter. The pull-down transistor PD2 includes a gate and source/drain regions. The second type nanowire foundation layer 244 serves as a source/drain region of the transistor PD2, one of the source/drain regions 60 serves as another source/drain region of the transistor PD2, and one of the gate structure 40 serves as the gate of the transistor PD2. The transistors PU1 and PD2 share the second type nanowire foundation layer 244. The pull-up transistor PU2 includes a gate and source/drain regions. The first type nanowire foundation layer 242 serves as a source/drain region of the transistor PU2, one of the source/drain regions 60 serves as another source/drain region of the transistor PU2, and one of the gate structure 40 serves as the gate of the transistor PU2. The transistors PU2 and PD1 share the first type nanowire foundation layer 242. The transistors PD2 and PU2 share the same gate structure 40 and the same source/drain region 60, and form another inverter. Further, the source/drain region 60 of the transistors PD1 and PU1 is electrically connected to the gate structure 40 of the transistors PD2 and PU2 through one of the gate vias 44 (see FIG. 16A), and the source/drain region 60 of the transistors PD2 and PU2 is electrically connected to the gate structure 40 of the transistors PD1 and PU1 through another of the gate vias 44. As such, the transistors PD1, PD1, PU2, and PD2 form two cross couple inverters.

The pass gate transistor PG1 includes a gate and source/drain regions. One of the source/drain regions 60 serves as a source/drain region of the transistor PG1, one strip of the bit line 100 serves as another source/drain region of the transistor PG1, and the word line 80 serves as the gate of the transistor PG1. The transistors PG1, PD1, and PU1 share the source/drain region 60. Another of the source/drain regions 60 serves as a source/drain region of the transistor PG2, another strip of the bit line 100 serves as another source/drain region of the transistor PG2, and the word line 80 serves as the gate of the transistor PG2. The transistors PG2, PD2, and PU2 share the source/drain region 60. The transistors PG1 and PG2 share the same word line 80. As such, the transistors PD1, PD1, PU2, PD2, PG1, and PG2 form a 6-T SRAM device.

Reference is made to FIG. 32, illustrating a schematic cross-sectional view of a complementary metal-oxide-semiconductor (CMOS) 200 having a stacked VGAA SRAM 300. The CMOS 200 includes gate structures, source and drain regions, isolation regions, contact vias in the interlayer dielectric layers. The VGAA SRAM 300 is disposed on the CMOS 200 in a monolithic fashion. This monolithic arrangement saves area on a semiconductor device because the lateral expansion is transferred to vertical direction. The insertion of the first type or second type nanowire foundation layer 242 or 244 on the semiconductor fins allows the monolithic integration between the CMOS 200 and VGAA SRAM 300 because the VGAA SRAM 300 has a lower thermal budget requirement, such that the device performance of CMOS 200 will not be affected. As shown in FIG. 32, the first and second type nanowire foundation layers 242 and 244 are formed as a portion of the semiconductor fins 24 a and 24 b. The first and second nanowires 28 a and 28 b are grown vertically over the first type and second type nanowire foundation layers 242 and 244 and used to form the gate structure 40 (cross coupled inverters), including the source/drain region 60. The word line 80 is stacked on the source/drain region 60 of the gate structure 40, and the bit line 100 is substantially perpendicular to the word line 80. The first nanowires 28 a are used as the template for the third, fifth and seventh nanowires 48 a, 68 a and 88 a. The second nanowires 28 b are used as the template for the fourth and sixth nanowires 48 b and 48 b. The characteristics of the first type and second type nanowire foundation layers 242 and 244 are passed over to the next level in each of the nanowire growing process.

By inserting different types of nanowire foundation layer to replace the original semiconductor fin, a compact VGAA pattern can be created. This pattern results in SRAM area scaling to smaller than 0.005 μm². The nanowire foundation layer allows a bottom-up growth fashion that uses the underlying nanowire (nanowire foundation layer) as the template for the next level. The pull-up and pull-down gates can be connected without the need of several metal layers in different levels. Channel materials such as InAs which has high electron mobility can be used as the core of the nanowire. This VGAA SRAM can also be integrated with regular logic CMOS, in which the logic CMOS is at level one and the VGAA SRAM is at level two in a monolithic fashion.

According to some embodiments, a method of manufacturing a semiconductor device includes forming a nanowire foundation layer on a semiconductor substrate. A first nanowire is formed on the nanowire foundation layer. A gate structure is formed over the nanowire foundation layer and wrapping the first nanowire. A second nanowire is formed on and in contact with the first nanowire in a bottom-up manner. A source/drain region is formed on the gate structure and wrapping the second nanowire.

In some embodiments, the method further includes forming a spacer on the gate structure and the first nanowire. A portion of the spacer is removed to expose the first nanowire, wherein the second nanowire is grown over the spacer.

In some embodiments, the method further includes forming an interlayer dielectric layer over the nanowire foundation layer and surrounding the gate structure and the spacer before removing the portion of the spacer.

In some embodiments, the method further includes forming a fin on the semiconductor substrate before forming the nanowire foundation layer.

In some embodiments, the method further includes recessing the fin, and the nanowire foundation layer is formed on the recessed fin.

In some embodiments, the method further includes forming a dielectric layer on the nanowire foundation layer. The dielectric layer is patterned to form a through hole that exposes a portion of the nanowire foundation layer, and a portion of the first nanowire is formed in the through hole.

In some embodiments, forming the first nanowire includes growing the first nanowire from the exposed portion of the nanowire foundation layer in a bottom-up manner.

In some embodiments, forming the source/drain region includes conformingly forming a contact metal layer on the second nanowire. A filling metal is formed on the contact metal layer. Portions of the contact metal layer and the filling metal are removed to expose a terminal of the second nanowire.

According to some embodiments, a method of manufacturing a semiconductor device includes forming a vertical gate-all-around (VGAA) transistor over a semiconductor substrate. A second nanowire is grown on and in contact with a first nanowire of the VGAA transistor in a bottom-up manner. A word line is formed over the VGAA transistor and wrapping the second nanowire.

In some embodiments, the method further includes forming a first spacer over the VGAA transistor before forming the second nanowire. The first spacer is patterned to expose the first nanowire of the VGAA transistor.

In some embodiments, forming the word line includes forming at least one metal layer over the VGAA transistor and wrapping the second nanowire. A spacer layer is formed over the at least one metal layer. The at least one metal layer and the spacer layer are patterned to form the word line and a second spacer on the word line.

In some embodiments, the method further includes removing a portion of the second spacer to expose the second nanowire.

In some embodiments, the method further includes growing a third nanowire on and in contact with the second nanowire. A bit line is formed over the word line and wrapping the third nanowire.

In some embodiments, the method further includes forming a third spacer on and in contact with the bit line. A portion of the third spacer is removed to expose the third nanowire.

According to some embodiments, a semiconductor device includes a semiconductor substrate, an N-type bottom vertical gate-all-around (VGAA) transistor, a P-type bottom VGAA transistor, and a top VGAA transistor. The N-type bottom VGAA transistor is over the semiconductor substrate and includes a first nanowire made of InAs. The P-type bottom VGAA transistor is over the semiconductor substrate and includes a second nanowire made of Ge. The top VGAA transistor is over the N-type bottom VGAA transistor. The top VGAA transistor includes a third nanowire, a fourth nanowire, and a bit line. The third nanowire is in contact with the N-type bottom VGAA transistor. The fourth nanowire is on and in contact with the third nanowire. The bit line wraps the fourth nanowire.

In some embodiments, the first nanowire of the N-type bottom VGAA transistor is in contact with the third nanowire of the top VGAA transistor.

In some embodiments, the N-type bottom VGAA transistor further comprises a source/drain region wrapping the first nanowire of the N-type bottom VGAA transistor, and the source/drain region of the N-type bottom VGAA transistor also serves as a source/drain region of the top VGAA transistor.

In some embodiments, the N-type bottom VGAA transistor further comprises a fifth nanowire under and in contact with the first nanowire of the N-type bottom VGAA transistor.

In some embodiments, the N-type bottom VGAA transistor further comprises a gate structure wrapping the fifth nanowire of the N-type bottom VGAA transistor.

In some embodiments, wherein the top VGAA transistor further comprises a word line wrapping the third nanowire of the top VGAA transistor.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

What is claimed is:
 1. A method of manufacturing a semiconductor device, the method comprising: forming a fin on a semiconductor substrate; recessing the fin; forming a nanowire foundation layer on the recessed fin; forming a first nanowire on the nanowire foundation layer; forming a gate structure over the nanowire foundation layer and wrapping the first nanowire; growing a second nanowire on and in contact with the first nanowire in a bottom-up manner; and forming a source/drain region on the gate structure and wrapping the second nanowire.
 2. The method of claim 1, further comprising: forming a spacer on the gate structure and the first nanowire; and removing a portion of the spacer to expose the first nanowire, wherein the second nanowire is grown over the spacer.
 3. The method of claim 2, further comprising forming an interlayer dielectric layer over the nanowire foundation layer and surrounding the gate structure and the spacer before removing the portion of the spacer.
 4. The method of claim 1, further comprising: forming a dielectric layer on the nanowire foundation layer; and patterning the dielectric layer to form a through hole that exposes a portion of the nanowire foundation layer, and a portion of the first nanowire is formed in the through hole.
 5. The method of claim 4, wherein forming the first nanowire comprises growing the first nanowire from the exposed portion of the nanowire foundation layer in a bottom-up manner.
 6. The method of claim 1, wherein forming the source/drain region comprises: conformingly forming a contact metal layer on the second nanowire; forming a filling metal on the contact metal layer; and removing portions of the contact metal layer and the filling metal to expose a terminal of the second nanowire.
 7. A method of manufacturing a semiconductor device, the method comprising: forming a vertical gate-all-around (VGAA) transistor over a semiconductor substrate; growing a second nanowire on and in contact with a first nanowire of the VGAA transistor in a bottom-up manner; forming a word line over the VGAA transistor and wrapping the second nanowire; growing a third nanowire on and in contact with the second nanowire; and forming a bit line over the word line and wrapping the third nanowire.
 8. The method of claim 7, further comprising: forming a first spacer over the VGAA transistor before forming the second nanowire; and patterning the first spacer to expose the first nanowire of the VGAA transistor.
 9. The method of claim 7, wherein forming the word line comprises: forming at least one metal layer over the VGAA transistor and wrapping the second nanowire; forming a spacer layer over the at least one metal layer; and pattering the at least one metal layer and the spacer layer to form the word line and a second spacer on the word line.
 10. The method of claim 9, further comprising removing a portion of the second spacer to expose the second nanowire.
 11. The method of claim 7, further comprising: forming a third spacer on and in contact with the bit line; and removing a portion of the third spacer to expose the third nanowire.
 12. A method of manufacturing a semiconductor device, the method comprising: forming a first nanowire foundation layer on a semiconductor substrate; forming a dielectric layer on the first nanowire foundation layer; patterning the dielectric layer to form a through hole that exposes a portion of the first nanowire foundation layer; forming a first nanowire on the first nanowire foundation layer, wherein a portion of the first nanowire is formed in the through hole; forming a gate structure over the first nanowire foundation layer and wrapping the first nanowire; growing a third nanowire on and in contact with the first nanowire in a bottom-up manner; and forming a source/drain region on the gate structure and wrapping the third nanowire.
 13. The method of claim 12, wherein forming the first nanowire comprises growing the first nanowire from the exposed portion of the first nanowire foundation layer in a bottom-up manner.
 14. The method of claim 12, further comprising: forming a second nanowire foundation layer on the semiconductor substrate prior to forming the dielectric layer; and forming a second nanowire on the second nanowire foundation layer.
 15. The method of claim 14, further comprising: forming first and second semiconductor fins over the semiconductor substrate; and recessing the first and second semiconductor fins, wherein the first and second nanowire foundation layers are formed respectively on the recessed first and second semiconductor fins.
 16. The method of claim 12, wherein forming the gate structure comprises: depositing a gate dielectric layer covering the first nanowire; and depositing a metal gate layer over the gate dielectric layer.
 17. The method of claim 16, further comprising etching the gate dielectric layer and the metal gate layer to expose the first nanowire.
 18. The method of claim 12, further comprising: depositing a filling metal surrounding the first nanowire after forming the gate structure; and etching the filling metal and the gate structure such that the first nanowire protrudes from a top surface of the filling metal.
 19. The method of claim 12, further comprising: forming a spacer layer over the first nanowire prior to forming the third nanowire; and performing a CMP process on the spacer layer to expose the first nanowire.
 20. The method of claim 12, further comprising forming a fifth fourth nanowire in direct contact with the third nanowire in a bottom-up manner. 